Elecrochemical Generation and Coulometric Methods
A Review from the Journal of Analytical Chemistry
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Elecrochemical generation is important for introducing precise known amounts of chemicals to a solution through coulometric methods. These coulometric methods are ideal for adding small amounts of desired chemicals in a nanosystem, but unwanted products are generated at the counter electrode because the systems are small and cannot use cell separators that other systems use. The authors propose to solve this problem with a capacitive electrode. 
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